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Khoom npe:Oxalic acid
Molecular hom:C2H2O4
CAS Nr:144-62-7 ib
Cov khoom siv molecular:
Oxalic acid yog dav faib nyob rau hauv cov nroj tsuag nyob rau hauv cov xwm, feem ntau muaj nyob rau hauv daim ntawv ntawm oxalic acid ntsev. CW Scheele muaj thawj zaug tsim oxalate hauv 1776.
Oxalate yog cov kua qaub uas muaj zog tshaj plaws ntawm cov dicarboxylic acid. Dhau li ntawm muaj cov khoom siv dav dav ntawm carboxylic acid, nws kuj muaj peev xwm txo tau cov cuab yeej thiab tuaj yeem txo qis xya valence manganese rau bivalent manganese. Cov cuab yeej no feem ntau siv rau kev ntsuas ntau ntawm cov poov tshuaj permanganate.
5 C2H2O4 + 2 KMnO4 + 3 H2SO4 → K2SO4 + 2 MNSO4 + 8H2O + 10 CO2;
Oxalic acid kuj tseem tuaj yeem txo cov hlau trivalent rau hauv bivalent hlau. Vim tias qhov siab solubility ntawm cov hlau bivalent hauv dej, peb tuaj yeem siv lub hauv paus ntsiab lus no kom tshem tawm xeb ntawm cov khaub ncaws.
Oxalic acid tuaj yeem hnov mob nrog phosphorus pentachloride los tsim phosphorus oxychloride. C2H2O4 + PCl5 → POCl3 + CO + CO2 + 2 HCL.
Oxalic acid tuaj yeem cuam tshuam nrog ntau cov hlau los tsim oxalic acid ntsev. Ntxiv nrog rau alkali hlau ntsev thiab bivalent hlau ntsev nrog tus so ntawm oxalic acid ntsev ua tsis zoo soluble hauv dej. Qee cov ntsev ntsev, txawm tias tsis zoo soluble hauv dej, tuaj yeem tsim cov complex uas yog soluble hauv dej.
Fe2 (C2O4) 3 + 3 K2C2O4 + 6 H2O →2 K3 [Fe (C2O4) 3] • 6 H2O.
Thaum cua sov, alkali hlau thiab alkaline ntiaj teb hlau oxalic acid ntsev tuaj yeem poob cov pa roj carbon monoxide thiab tsim cov carbonates nrog cov carbonate txuas ntxiv mus rau cua sov kom ntxiv decomposed rau hauv oxide thiab carbon dioxide. Cov oxalic acid ntsev ntawm nickel, cobalt thiab nyiaj thaum kawg tuaj yeem tsim cov hlau tsis yog hlau oxide.
Cov khoom decomposing ntawm oxalate yog carbon dioxide, carbon monoxide thiab dej.
Oxalate thiab oxalic acid ntsev yog tshuaj lom. Cov nas, los ntawm kev tswj qhov ncauj, muaj LD50 ntawm 2000 ~ 4000 mg / kg.
1. Oxalic acid tuaj yeem siv tau los ua tus neeg sawv cev thiab tshuaj dawb, mordant rau dyeing thiab luam ntawv kev lag luam, kuj tseem siv rau hauv kev ua kom tsis tshua muaj hlau, cov synthesis ntawm ntau yam oxalate ester amide, oxalate thiab nyom, thiab lwm yam.
2. Siv ua analytical reagent.
3. Siv raws li kev kuaj reagents, chromatography tsom xam reagent, dye intermediates thiab cov khoom txheem.
4. Oxalic acid feem ntau yog siv los tsim cov tshuaj xws li tshuaj tua kab mob thiab borneol thiab hnyav rau rho tawm cov hlau tsis tshua muaj, txo tus neeg sawv cev thiab dye, tanning tus neeg saib xyuas, thiab lwm yam. Tsis tas li ntawd, oxalic acid kuj siv tau rau kev sib txuas ntawm ntau yam oxalate. ester, oxalate, thiab oxamide nrog diethyl oxalate, sodium oxalate thiab calcium oxalate muaj cov txiaj ntsig loj tshaj plaws. Oxalate tseem tuaj yeem siv rau kev tsim cov cobalt-molybdenum-alumina catalyst, ntxuav cov hlau thiab marble nrog rau cov tshuaj dawb ntawm textiles.
Chemwin tuaj yeem muab ntau hom hydrocarbons thiab cov kuab tshuaj tshuaj lom neeg rau cov neeg siv khoom.Ua ntej ntawd, thov nyeem cov lus qhia hauv qab no txog kev ua lag luam nrog peb:
1. Kev ruaj ntseg
Kev nyab xeeb yog peb qhov tseem ceeb tshaj plaws. Ntxiv nrog rau kev muab cov neeg siv khoom paub txog kev nyab xeeb thiab ib puag ncig tus phooj ywg siv peb cov khoom, peb kuj tau cog lus los xyuas kom meej tias kev nyab xeeb ntawm cov neeg ua haujlwm thiab cov neeg cog lus raug txo qis rau qhov tsim nyog thiab ua tau yam tsawg kawg nkaus. Yog li, peb xav kom tus neeg siv khoom kom ntseeg tau tias qhov tsim nyog tshem tawm thiab khaws cov qauv kev nyab xeeb tau ua tiav ua ntej peb xa khoom (thov xa mus rau HSSE appendix nyob rau hauv cov nqe lus dav dav thiab kev muag khoom hauv qab no). Peb cov kws tshaj lij HSSE tuaj yeem muab kev taw qhia txog cov qauv no.
2. Txoj kev xa khoom
Cov neeg siv khoom tuaj yeem xaj thiab xa cov khoom los ntawm chemwin, lossis lawv tuaj yeem tau txais cov khoom los ntawm peb cov chaw tsim khoom. Cov hom kev thauj mus los muaj xws li tsheb thauj mus los, tsheb ciav hlau lossis kev thauj mus los ntau yam (xws li kev sib cais).
Nyob rau hauv cov ntaub ntawv ntawm cov neeg yuav tsum tau, peb muaj peev xwm qhia kom meej qhov yuav tsum tau ntawm barges los yog tankers thiab siv tshwj xeeb kev nyab xeeb / tshuaj xyuas cov qauv thiab cov kev cai.
3. Yam tsawg kawg nkaus kom muaj nuj nqis
Yog tias koj yuav khoom los ntawm peb lub vev xaib, qhov kev txiav txim yam tsawg kawg nkaus yog 30 tons.
4. Kev them nyiaj
Txoj kev them nyiaj tus qauv yog txiav tawm ncaj qha hauv 30 hnub txij li daim ntawv xa nyiaj.
5. Cov ntaub ntawv xa tuaj
Cov ntaub ntawv hauv qab no tau muab nrog rau txhua qhov kev xa khoom:
· Bill of Lading, CMR Waybill lossis lwm yam ntaub ntawv thauj mus los
· Certificate of Analysis los yog Conformity (yog xav tau)
· Cov ntaub ntawv hais txog HSSE raws li txoj cai
· Cov ntaub ntawv kev lis kev cai raws li txoj cai (yog tias xav tau)